Beilstein J. Org. Chem.2016,12, 1178–1184, doi:10.3762/bjoc.12.113
-bromo-1,1-dimethylindene.
Keywords: base-freedehydrobromination; cis/trans stereochemistry; five-membered ring conformation; indenes; NMR couplings; Introduction
The basic mechanistic features of competing suprafacial and antarafacial additions of elemental bromine to an olefin are reasonably well
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Graphical Abstract
Scheme 1:
Bromine adducts (trans-1 and cis-1) of 1,1-dimethylindene (2) and their envelope conformations: ax ...